Abstract
The increasing demand for sustainable energy and the urgent need to reduce greenhouse gas emissions have intensified research into biodiesel as an alternative to fossil diesel. Non-edible oilseed resources, such as False White Teak (FWT) seeds, offer a promising and sustainable feedstock that does not compete with food supplies. However, the high viscosity and density of crude FWT oil limit its direct use in diesel engines. In this study, biodiesel was produced from FWT oil via alkali-catalysed trans-esterification, and process parameters were optimized to enhance fuel quality and yield. Trans-esterification was conducted at 60 °C using oil-to-methanol molar ratios ranging from 6:1. The maximum biodiesel yield of 78.70% was obtained at a 6:1 ratio. In contrast, lower ratios were evaluated to examine phase separation and soap formation. The produced biodiesel was purified and characterized according to ASTM D6751 standards. The fuel exhibited a density of 867 kg/m³, kinematic viscosity of 4.2 cSt at 40 °C, calorific value of 35 MJ/kg, flash point of 119 °C, fire point of 127 °C, and moisture content of 0.05%, demonstrating good compliance with ASTM D6751 standards biodiesel specifications. In addition, a simplified life cycle cost analysis revealed that the estimated biodiesel production cost was competitive with conventional diesel when by-product recovery was considered, highlighting its techno-economic feasibility. These results demonstrate that FWT oil is a viable non-edible feedstock for biodiesel production, offering both technical and economic potential for sustainable biofuel development in emerging economies.
References
Shaah, M. A. H., Hossain, M. S., Allafi, F. A. S., Alsaedi, A., Ismail, N., Ab Kadir, M. O., & Ahmad, M. I. (2021). A review on non-edible oil as a potential feedstock for biodiesel: Physicochemical properties and production technologies. RSC Advances, 11(40), 25018–25037. https://doi.org/10.1039/D1RA04311K
Emmanouilidou, E., Lazaridou, A., Mitkidou, S., & Kokkinos, N. C. (2024). A comparative study on biodiesel production from edible and non-edible biomasses. Journal of Molecular Structure, 1306, 137870. https://doi.org/10.1016/j.molstruc.2024.137870
Androniceanu, A., Veith, C., Ionescu, ?. A., Marinescu, P., Sima, A. G., & Paru, A. (2024). Shaping sustainable futures: Public policies and renewable energy insights based on global bibliometric analysis. Sustainability, 16(12), 4957. https://doi.org/10.3390/su16124957
Shahee, S., Singh, A. P., Gautam, P. S., Singh, S., & Sharma, R. (2024). Exploring non-edible oils as promising feedstock for biodiesel production and their application as alternative fuel in diesel engines: A comprehensive review. In B. S. Sikarwar & S. K. Sharma (Eds.), Scientific and technological advances in materials for energy storage and conversions (Lecture Notes in Mechanical Engineering; FLUTE 2023). Springer. https://doi.org/10.1007/978-981-97-2481-9_29
Okoro, O. V., Sun, Z., & Birch, J. (2018). Catalyst-free biodiesel production methods: A comparative technical and environmental evaluation. Sustainability, 10(1), 127. https://doi.org/10.3390/su10010127
Farouk, S. M., Tayeb, A. M., Abdel-Hamid, S. M. S., & Osman, R. M. (2024). Recent advances in transesterification for sustainable biodiesel production, challenges, and prospects: A comprehensive review. Environmental Science and Pollution Research, 31(9), 12722–12747. https://doi.org/10.1007/s11356-024-32027-4
Mofijur, M., Masjuki, H. H., Kalam, M. A., & Atabani, A. E. (2013). Evaluation of biodiesel blending, engine performance and emissions characteristics of Jatropha curcas methyl ester: Malaysian perspective. Energy, 55, 879–887. https://doi.org/10.1016/j.energy.2013.02.059
Araújo, C. D. M. de, Andrade, C. C. de, Silva, E. de S., & Dupas, F. A. (2013). Biodiesel production from used cooking oil: A review. Renewable and Sustainable Energy Reviews, 27, 445–452. https://doi.org/10.1016/j.rser.2013.06.014
Stuart, G. U. Jr. (2025). False White Teak (Mallotus nudiflorus). StuartXchange – Philippine Medicinal Plants database. https://www.stuartxchange.com/FalseWhiteTeak
Garavaglia, J., Markoski, M. M., Oliveira, A., & Marcadenti, A. (2016). Grape seed oil compounds: Biological and chemical actions for health. Nutrition and Metabolism Insights, 9, 59–64. https://doi.org/10.4137/NMI.S32910
Sarin, A., Singh, M., Sharma, N., & Singh, N. P. (2017). Prospects of Tectona grandis as a feedstock for biodiesel. Frontiers in Energy Research, 5, 28. https://doi.org/10.3389/fenrg.2017.00028
Farouk, S. M., Tayeb, A. M., Abdel-Hamid, S. M. S., & Osman, R. M. (2024). Recent advances in transesterification for sustainable biodiesel production, challenges, and prospects: A comprehensive review. Environmental Science and Pollution Research, 31(9), 1–26. https://doi.org/10.1007/s11356-024-32027-4
Demirba?, A., Bafail, A., Ahmad, W., & Sheikh, M. (2016). Biodiesel production from non-edible plant oils. Energy Exploration & Exploitation, 34(2), 290–318. https://doi.org/10.1177/0144598716630166
Ceran, Z. D., Demir, V., & Akgün, M. (2025). Optimization and kinetic study of biodiesel production from Jatropha curcas oil in supercritical methanol environment using ZnO/?-Al?O? catalyst. Biomass Conversion and Biorefinery, 15, 3903–3914. https://doi.org/10.1007/s13399-024-05307-9
Sangeetha, B., & Baskar, G. (2023). Process design, kinetics, simulation, and techno-economic analysis of biodiesel production from Pongamia pinnata seed oil using a magnetically recyclable acidic ionic liquid catalyst. Energy Conversion and Management, 291, 118040. https://doi.org/10.1016/j.enconman.2023.118040
Oliva-Rodríguez, A. G., Salinas De León, F., Morales-Martínez, T. K., Rodríguez-De la Garza, J. A., Medina-Morales, M. A., Cruz-Requena, M., Neyra-Escobedo, G. A., & Ríos-González, L. J. (2025). Coproduction of biodiesel and bioethanol from Ricinus communis seed through an integrated process. Processes, 13(9), 2877. https://doi.org/10.3390/pr13092877
Arslan, M., Ayyub, H., Jamshaid, M., Arslan, A., Kalam, M. A., & Ahmad, F. (2025). Production, performance and emission of biodiesel from a mixture of castor oil and neem oil. RSC Advances, 15, 35296–35311. https://doi.org/10.1039/D5RA04004C
Rahul, S., Azeez, M. K. A., Nithyanand, P., et al. (2025). Optimizing biodiesel production from Madhuca indica oil using marine bacteria as a whole-cell biocatalyst: Engine testing and performance analysis. Biotechnology for Biofuels and Bioproducts, 18, 78. https://doi.org/10.1186/s13068-025-02642-5
Khan, I. U. (2024). Biodiesel production and selected fuel qualities from prospective non-edible oils: Hevea brasiliensis, Madhuca longifolia, Azadirachta indica, and Gossypium hirsutum. International Journal of Green Energy, 21(14), 3054–3071. https://doi.org/10.1080/15435075.2024.2349194
Sambasivam, K. M., Kuppan, P., Laila, L. S., Shashirekha, V., Tamilarasan, K., & Abinandan, S. (2023). Kernel-based biodiesel production from non-edible oil seeds: Techniques, optimization, and environmental implications. Energies, 16(22), 7589. https://doi.org/10.3390/en16227589
Bora, M. M., Deka, R., Ahmed, N., & Kakati, D. K. (2014). Karanja (Millettia pinnata (L.) Panigrahi) seed oil as a renewable raw material for the synthesis of alkyd resin. Industrial Crops and Products, 61, 106–114. https://doi.org/10.1016/j.indcrop.2014.06.048
Sharma, A., Kaushik, N., & Rathore, H. (2020). Karanja (Milletia pinnata (L.) Panigrahi): A tropical tree with varied applications. Phytochemistry Reviews, 19(3), 643–658. https://doi.org/10.1007/s11101-020-09670-z
Al Fadal, S. M., & Al-Fredan, M. A. (2015). Ecophysiological studies on Saudi wild safflower (Carthamus oxyacantha Bieb) seed ecotypes. American Journal of Environmental Sciences, 11(3), 125–132. https://doi.org/10.3844/ajessp.2015.125.132
Hanif, M., Bhatti, I. A., Zahid, M., & et al. (2022). Production of biodiesel from non-edible feedstocks using environment friendly nano-magnetic Fe/SnO catalyst. Scientific Reports, 12, 16705. https://doi.org/10.1038/s41598-022-20856-7
Wang, Y., Devanesan, S., Aljawdah, H. M., Rithika, M., & Brindhadevi, K. (2025). Enhancing combustion performance and emission profiles using Citrullus colocynthis biodiesel blends with hydrogen. International Journal of Hydrogen Energy. https://doi.org/10.1016/j.ijhydene.2025.04.233
ASTM International. (2023). Standard specification for biodiesel fuel blend stock (B100) for middle distillate fuels (ASTM D6751-20a). ASTM International. https://www.astm.org/d6751-20a.html

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